Īmong the plethora of electrochemical synthesis are, for instance, the chlorine-alkali electrolysis, the conversion of muconic acid to diacid monomers, and the CO 2 reduction to formate, CO, or hydrocarbons. When electrochemical syntheses are integrated into process lines comprising microbial conversions in a Power-to-X approach, electrobiorefineries are set into place. This allows combining electrochemical synthesis with chemical, physical, and biological process steps. Power-to-X aims at utilizing (surplus) electric energy for electrochemical synthesis including electrochemical upgrading of compounds that underwent preceding process steps as well as the electrochemical supply of intermediates for follow-up conversions. Such links can be created by Power-to-Chemicals, Power-to-Fuels, or more generally Power-to-X that have gained special attention in the last decade. Hence, it is particularly important to link electric power production and storage with the chemical sector. Thereby interweaving of the different sectors of a bio-based economy is of utmost importance to achieve the ambitious goals, for instance, formulated in the Green New Deal of the European Union. the feedstock of carbon, nitrogen, etc.) is as important as it is for the energetic basis that is mainly electric power and heat. Achieving sustainability for the material basis (e. g. The future of our economy has to be circular and based on renewable resources. Using platinized titanium requires >36 times less capital expenditure at only <10 % increased operational expenditure an electrode lifetime of 10000 h can be expected. An uncovered surface of as little as 1–3 % already led to a deterioration of the CE of approximately 50 %. Using optical profilometry and scanning electron microscopy coupled with energy‐dispersive X‐ray spectroscopy, it was shown that the degree of coverage of the titanium surface with platinum played the most important role. 56.7 mL liquid fuel was produced per mole n‐hexanoic acid, converting to an energy demand of 6.66 kWh and 1.22 € per L. Platinized titanium performed best, achieving a coulombic efficiency (CE) of 93.1☖.7 % ( n=6) for the degradation of n‐hexanoic acid and 48.3☓.2 % ( n=6) for the production of n‐decane, which is close to the performance of pure platinum (89.7☑4.4 and 55.5☓.5 % n=6). Customization is also possible on select models depending on the sellers.Five commercial materials were assessed for electrochemical conversion of n‐hexanoic acid by Kolbe electrolysis.
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